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平成19年度分子創薬化学セミナー(前期)
 平成19年度分子創薬化学セミナー(前期)

第25回(2007. 09. 15)
担当者:竹安安範
文献名:"Catalytic Intermolecular Reductive Coupling of Enones and Alkynes"
A. Herath, B. B. Thompson, J. Montgomery
J. Am. Chem. Soc., 129 (28), 8712-8713 (2007).

第24回(2007. 09. 15)
担当者:木下陽子
文献名:"Asymmetric Organocatalytic α-Arylation of Aldehydes"
J. Aleman, S. Cabrera, E. Maerten, J. Overgaard, A. Jφrgensen
Angew. Chem. Int. Ed., 46 (29), 5520-5523 (2007).


第23回(2007. 07. 28)
担当者:岡崎真治
文献名:"Total Synthesis of Marine Natural Products without Using Protecting Groupss"
P. S. Baran, T. J. Maimone, J. M. Richter
Nature, 446 (22), 404-408 (2007).

第22回(2007. 07. 28)
担当者:久次米永子
文献名:"The Development of Scalemic Multidentate Niobium Complexes as Catalysts for the Highly Stereoselective Ring Opening of meso-Epoxides and meso-Aziridines"
K. Arai, S. Lucarini, M. M. Salter, K. Ohta, Y. Yamashita, S. Kobayashi
J. Am. Chem. Soc., 129 (26), 8103-8111 (2007).


第21回(2007. 07. 21)
担当者:上野麻衣
文献名:""Super Silyl" Group for Diastereoselective Sequential Reactions: Access to Complex Chiral Architecture in One Pot"
M. B. Boxer, H. Yamamoto
J. Am. Chem. Soc., 129 (10), 2762-2763 (2007).

第20回(2007. 07. 21)
担当者:森本晃允
文献名:"Pybox/Lanthanide-Catalysed Diels-Alder Reactions with an Unsaturated α-Oxo Ester or 3-Alkenoyl-2-oxazolidinone as Dienophile: The Sense of Stereoinduction in Five- or Six-Membered Bidentate Reagent Coordination"
G. Desimoni, G, Faita, M. Mella, F. Piccinini, M. Toscanini
Eur. J. Org. Chem., (9), 1529-1534 (2007).

第19回(2007. 07. 21)
担当者:平松由佳子
文献名:"A One-Pot Asymmetric Sequential Amination-Alkylation of Aldehydes: Expedient Synthesis of Aliphatic Chiral Amines"
V. N. Wakchaure, R. R. Mohanty, A. J. Shaikh
Eur. J. Org. Chem., (6), 959-964 (2007).


第18回(2007. 07. 14)
担当者:大勢祐希子
文献名:"Nucleophilic Acylation of o-Quinone Methides: An Umpolung Strategy for the Synthesis of α-Aryl Ketones and Benzofurans"
A. E. Mattson, K. A. Scheidt
J. Am. Chem. Soc., 129 (15), 4508-4509 (2007).

第17回(2007. 07. 14)
担当者:七瀧浩志
文献名:"Synthesis of Novel Functionalized Derivatives of 5-Nitro-3,4-dihydropyrimidin-2(1H)-one by the Cyclocondensation of 1-Chlorobenzyl Isocyanates with N,S- and N,N-Nitroketeneacetals"
V. A. Sukach, A. V. Bol'but, A. Y. Petin, M. V. Vovk
Synthesis, (6), 835-844 (2007).

第16回(2007. 07. 14)
担当者:中野沙織
文献名:"Organocatalytic Asymmetric Conjugate Nucleophilic Glyoxylation"
D. Enders, M. H. Bonten, G. Raabe
Synlett, (6), 885-888 (2007).


第15回(2007. 07. 07)
担当者:市川喬士
文献名:"Catalytic Enantioselective Petasis-Type Reaction of Quinolines Catalyzed by a Newly Designed Thiourea Catalyst"
Y. Yamaoka, H. Miyabe, Y. Takemoto
J. Am. Chem. Soc., 129 (21), 6686-6687 (2007).

第14回(2007. 07. 07)
担当者:腰岡桜
文献名:"An Efficient Synthesis of Amides and Esters via Triacyloxyboranes"
Z. Huang, L. E. Reilly, R. N. Buckle
Eur. J. Org. Chem., (7), 1026-1030 (2007).

第13回(2007. 07. 07)
担当者:折戸太一
文献名:"Mycothiazole: Synthesis of the C8-C18 Subunit and Further Evidence of the (Z)-Δ14 Double Bond Configuration"
M. Rega, P. Candal, C. Jimenez, J. Rodriguez
Eur. J. Org. Chem., (6), 934-942 (2007).


第12回(2007. 06. 30)
担当者:山田敏彰
文献名:"Diastereo- and Enantioselective Synthesis of Nitroso Diels-Alder-Type Bicycloketones Using Dienamine: Mechanistic Insight into Sequential Nitroso Aldol/Michael Reaction and Application for Optically Pure 1-Amino-3,4-diol Synthesis"
N. Momiyama, Y. Yamamoto, H. Yamamoto
J. Am. Chem. Soc., 129 (5), 1190-1195 (2007).

第11回(2007. 06. 30)
担当者:山下大輔
文献名:"Diastereomeric Fluoroolefins as Peptiede Bond Mimics Prepared by Asymmetric Reductive Amination of α-Fluoroenones"
G. Dutheuil, S. Couve-Bonnaire, X. Pannecoucke
Angew. Chem. Int. Ed., 46 (8), 1290-1292 (2007).


第10回(2007. 06. 23)
担当者:増田隆司
文献名:"DTotal Syntheses, Fragmentation Studies, and Antitumor/Antiproliferative Activities of FR901464 and Its Low Picomolar Analogue"
B. J. Albert, A. Sivaramakrishnan, T. Naka, N. L. Czaicki, K. Koide
J. Am. Chem. Soc., 129 (9), 2648-2659 (2007).

第9回(2007. 06. 23)
担当者:竹安正範
文献名:"syn-Selective Catalytic Asymmetric Nitro-Mannich Reactions Using a Heterobimetallic Cu-Sm-Schiff Base Complex"
S. Handa, V. Gnanadesikan, S. Matsunaga, M. Shibasaki
J. Am. Chem. Soc., 129 (16), 4900-4901 (2007).


第8回(2007. 06. 16)
担当者:津村武史
文献名:"Diastereomerically and Enantiomerically Pure 2,3-Disubstituted Pyrrolidines from 2,3-Aziridin-1-ols Using a Sulfoxonium Ylide: A One-Carbon Homologative Relay Ring Expansion"
J. M. Schomaker, S. Bhattacharjee, L. Yan, B. Borhan
J. Am. Chem. Soc., 129 (7), 1996-2003 (2007).

第7回(2007. 06. 16)
担当者:木下陽子
文献名:"RSynthesis of 7-Azaserotonin: Its Photophysical Properties Associated with Excited State Proton Transfer Reaction"
P.-W. Wu, W.-T. Hsieh, Y.-M. Cheng, C.-Y. Wei, P.-T. Chou
J. Am. Chem. Soc., 129 (45), 14426-14427 (2007).


第6回(2007. 06. 09)
担当者:大久保好規
文献名:"Synthesis of an Optically Active Al(salalen) Complex and Its Application to Catalytic Hydrophosphonylation of Aldehydes and Aldimines"
B. Saito, H. Egami, T. Katsuki
J. Am. Chem. Soc., 129 (7), 1978-1986 (2007).

第5回(2007. 06. 09)
担当者:上野麻衣
文献名:"Regio- and Chemoselective Silylmetalation of Functionalized Terminal Alkenes"
S. Nakamura, M. Uchiyama
J. Am. Chem. Soc., 129 (1), 28-29 (2007).


第4回(2007. 06. 02)
担当者:中尾允泰
文献名:"Biaryl Synthesis via Pd-Catalyzed Decarboxylative Coupling of Aromatic Carboxylates with Aryl Halides"
L. J. Goossen, N. Rodriguez, B. Melzer, C. Linder, G. Deng, L. M. Levy
J. Am. Chem. Soc., 129 (15), 4824-4833 (2007).

第3回(2007. 06. 02)
担当者:大勢祐希子
文献名:"A Dramatic Effect of Lewis-Acid Catalysts on Nickel-Catalyzed Carbocyanation of Alkynes"
Y. Nakao, A. Yada, S. Ebata, T. Hiyama
J. Am. Chem. Soc., 129 (9), 2428-2429 (2007).


第2回(2007. 05. 19)
担当者:池江克文
文献名:"Total Synthesis of Dimeric Pyrrole-Imidazole Alkaloids: Sceptrin, Ageliferin, Nagelamide E, Oxysceptrin, Nakamuric Acid, and the Axinellamine Carbon Skeleton"
D. P. O'Malley, K. Li, M. Maue, A. L. Zografos, and P. S. Baran
J. Am. Chem. Soc., 129 (15), 4762-47753 (2007).

第1回(2007. 05. 19)
担当者:市川喬士
文献名:"Asymmetric Conjugate Addition of Silyl Enol Ethers Catalyzed by Tethered Bis(8-quinolinolato) Aluminum Complexes"
N. Takenaka, J. P. Abell, and H. Yamamoto
J. Am. Chem. Soc., 129 (4), 742-743 (2007).

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